SYNTHESIS OF VARIOUS IODYL COMPOUNDS OF IODOARENES AND TETRAZOLES USING OXONE AS AN OXIDANT

dc.contributor.advisorHandy, Scotten_US
dc.contributor.authorDhakal, Ram Chandraen_US
dc.contributor.committeememberPatterson, Dwighten_US
dc.contributor.committeememberKline, Paulen_US
dc.contributor.departmentChemistryen_US
dc.date.accessioned2014-06-02T18:50:34Z
dc.date.available2014-06-02T18:50:34Z
dc.date.issued2013-07-05en_US
dc.description.abstractIodyls are interesting compounds. To date, much of this interest has been focused on the application of iodyls as unique oxidants in organic synthesis. In this work, we are interested in their application as energetic materials.en_US
dc.description.abstractWhen Oxone<super>&reg;</super> was used as an oxidant in the preparation of iodyl compounds, more than 99% pure product based on NMR analysis was obtained without extra purification of the products. This method is also able to recover the unreacted starting material by washing the precipitate of iodyl compound with appropriate organic solvents.en_US
dc.description.abstractEleven iodyl compounds with good yields have been synthesized using Oxone<super>&reg;</super>. After successfully establishing the reactions, the scales of some starting materials were increased up to 10 mmol. After increasing the reaction scales, the yields of the products did not decrease, indicating that this method is readily scalable. Due to the presence of two iodyl groups on the benzene ring, 1,4&ndash;diiodylbenzene was not soluble in DMSO. The melting points of the iodyl compounds are the decomposition points. <italic>p</italic>-Diiodylbenzene decomposed vigorously compared to the iodyl compounds having only one iodyl group, such as iodylbenzene, 2&ndash;iodylnitrobenzene, 3&ndash;iodylbenzonitrile, and 4&ndash;iodylbenzonitrile. From this observation, when the iodyl group on the benzene ring is more than one, the explosive character of the compounds increases. Iodyl compounds of the tetrazole derivatives, such as 5&ndash;(3&ndash;iodylphenyl)&ndash;1<italic>H</italic>-tetrazole and 5&ndash;(4&ndash;iodylphenyl)-1<italic>H</italic>-tetrazole, also decomposed vigorously at the corresponding decomposition points.en_US
dc.description.degreeM.S.en_US
dc.identifier.urihttp://jewlscholar.mtsu.edu/handle/mtsu/3550
dc.publisherMiddle Tennessee State Universityen_US
dc.subjectGreen Synthesisen_US
dc.subjectIodyl Compoundsen_US
dc.subjectIodyl Compounds from Oxoneen_US
dc.subjectIodyl Compounds of Tetrazolesen_US
dc.subjectPotentially Explosive Compounden_US
dc.subjectTetrazoles Derivativesen_US
dc.subject.umiOrganic chemistryen_US
dc.subject.umiChemistryen_US
dc.thesis.degreegrantorMiddle Tennessee State Universityen_US
dc.thesis.degreelevelMastersen_US
dc.titleSYNTHESIS OF VARIOUS IODYL COMPOUNDS OF IODOARENES AND TETRAZOLES USING OXONE AS AN OXIDANTen_US
dc.typeThesisen_US

Files

Original bundle

Now showing 1 - 1 of 1
Loading...
Thumbnail Image
Name:
Dhakal_mtsu_0170N_10112.pdf
Size:
15.33 MB
Format:
Adobe Portable Document Format

Collections