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SYNTHESIS OF VARIOUS IODYL COMPOUNDS OF IODOARENES AND TETRAZOLES USING OXONE AS AN OXIDANT

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dc.contributor.advisor Handy, Scott en_US
dc.contributor.author Dhakal, Ram Chandra en_US
dc.date.accessioned 2014-06-02T18:50:34Z
dc.date.available 2014-06-02T18:50:34Z
dc.date.issued 2013-07-05 en_US
dc.identifier.uri http://jewlscholar.mtsu.edu/handle/mtsu/3550
dc.description.abstract Iodyls are interesting compounds. To date, much of this interest has been focused on the application of iodyls as unique oxidants in organic synthesis. In this work, we are interested in their application as energetic materials. en_US
dc.description.abstract When Oxone<super>&reg;</super> was used as an oxidant in the preparation of iodyl compounds, more than 99% pure product based on NMR analysis was obtained without extra purification of the products. This method is also able to recover the unreacted starting material by washing the precipitate of iodyl compound with appropriate organic solvents. en_US
dc.description.abstract Eleven iodyl compounds with good yields have been synthesized using Oxone<super>&reg;</super>. After successfully establishing the reactions, the scales of some starting materials were increased up to 10 mmol. After increasing the reaction scales, the yields of the products did not decrease, indicating that this method is readily scalable. Due to the presence of two iodyl groups on the benzene ring, 1,4&ndash;diiodylbenzene was not soluble in DMSO. The melting points of the iodyl compounds are the decomposition points. <italic>p</italic>-Diiodylbenzene decomposed vigorously compared to the iodyl compounds having only one iodyl group, such as iodylbenzene, 2&ndash;iodylnitrobenzene, 3&ndash;iodylbenzonitrile, and 4&ndash;iodylbenzonitrile. From this observation, when the iodyl group on the benzene ring is more than one, the explosive character of the compounds increases. Iodyl compounds of the tetrazole derivatives, such as 5&ndash;(3&ndash;iodylphenyl)&ndash;1<italic>H</italic>-tetrazole and 5&ndash;(4&ndash;iodylphenyl)-1<italic>H</italic>-tetrazole, also decomposed vigorously at the corresponding decomposition points. en_US
dc.publisher Middle Tennessee State University en_US
dc.subject Green Synthesis en_US
dc.subject Iodyl Compounds en_US
dc.subject Iodyl Compounds from Oxone en_US
dc.subject Iodyl Compounds of Tetrazoles en_US
dc.subject Potentially Explosive Compound en_US
dc.subject Tetrazoles Derivatives en_US
dc.title SYNTHESIS OF VARIOUS IODYL COMPOUNDS OF IODOARENES AND TETRAZOLES USING OXONE AS AN OXIDANT en_US
dc.type Thesis en_US
dc.contributor.committeemember Patterson, Dwight en_US
dc.contributor.committeemember Kline, Paul en_US
dc.thesis.degreelevel Masters en_US
dc.thesis.degreegrantor Middle Tennessee State University en_US
dc.subject.umi Organic chemistry en_US
dc.subject.umi Chemistry en_US
dc.description.degree M.S. en_US
dc.contributor.department Chemistry en_US


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